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Markovnikov's rule
H⁺ to CH₂
0
H⁺ to CH
0
kJ/mol
H⁺ to CH₂
→ 2-bromopropane (Markovnikov) · barrier 133 kJ/mol
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H⁺ to CH
→ 1-bromopropane · barrier 163 kJ/mol
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Propene···HBr
HBr sits loosely over the C=C.